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4. Velocity in Quantum Mechanics

Is Velocity Meaningless in Quantum Mechanics?
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Is Velocity Meaningless in Quantum Mechanics?

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1. Classical Trajectory vs. Quantum Uncertainty

Section titled “1. Classical Trajectory vs. Quantum Uncertainty”

In classical Newtonian mechanics, a particle has simultaneously well-defined position x(t)x(t) and velocity v(t)=dxdtv(t) = \frac{dx}{dt}.

In quantum mechanics, position x^\hat{x} and momentum p^\hat{p} are represented by non-commuting Hermitian operators:

[x^,p^]=x^p^−p^x^=iℏ[\hat{x}, \hat{p}] = \hat{x}\hat{p} - \hat{p}\hat{x} = i\hbar

According to the Robertson-Schrödinger uncertainty relation:

σxσp≥ℏ2\sigma_x \sigma_p \ge \frac{\hbar}{2}

Because an exact position measurement (σx→0\sigma_x \to 0) forces infinite momentum dispersion (σp→∞\sigma_p \to \infty), the concept of an instantaneous path velocity ΔxΔt\frac{\Delta x}{\Delta t} is fundamentally ill-defined.


2. Expectation Values & Ehrenfest’s Theorem

Section titled “2. Expectation Values & Ehrenfest’s Theorem”

While point-by-point trajectory ceases to exist, the average or expectation value of momentum obeys a quantum correspondence principle:

⟨p⟩=∫−∞∞ψ∗(x)(−iℏ∂∂x)ψ(x) dx\langle p \rangle = \int_{-\infty}^{\infty} \psi^*(x) \left( -i\hbar \frac{\partial}{\partial x} \right) \psi(x) \, dx

By Ehrenfest’s Theorem, the time derivative of the average position recovers classical velocity:

d⟨x⟩dt=⟨p⟩m\frac{d\langle x \rangle}{dt} = \frac{\langle p \rangle}{m}