4. Velocity in Quantum Mechanics
1. Classical Trajectory vs. Quantum Uncertainty
Section titled “1. Classical Trajectory vs. Quantum Uncertainty”In classical Newtonian mechanics, a particle has simultaneously well-defined position and velocity .
In quantum mechanics, position and momentum are represented by non-commuting Hermitian operators:
According to the Robertson-Schrödinger uncertainty relation:
Because an exact position measurement () forces infinite momentum dispersion (), the concept of an instantaneous path velocity is fundamentally ill-defined.
2. Expectation Values & Ehrenfest’s Theorem
Section titled “2. Expectation Values & Ehrenfest’s Theorem”While point-by-point trajectory ceases to exist, the average or expectation value of momentum obeys a quantum correspondence principle:
By Ehrenfest’s Theorem, the time derivative of the average position recovers classical velocity:
